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Verpackungen und Behälter Industrie
The Practical Guide to Surface Science (2026)

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This is a practical guide to Surface Science for researchers working in the Packaging and Containers Industry.

In diesem brandneuen Leitfaden erfährst du alles über:

  • Entscheidende Prinzipien der Oberflächenforschung
  • The significance of surface science measurements for the Packaging and Containers industry
  • Anwendbare ASTM-Normen und -Richtlinien

Lassen Sie uns gleich eintauchen.

packaging containers

Executive Summary

What it covers: A practical surface-science guide for packaging and container teams covering contact angle (static + advancing/receding), surface tension (static + dynamic), surface energy, and sliding angle—and how each measurement connects to packaging performance. It ties these measurements to real packaging problems like oil/grease resistance, moisture sensitivity of bio-films, leak risk, ink removal for recycling, and label adhesion on curved packs.
Key insights: For real packaging surfaces (porous papers, coated films, treated plastics), single “static” angles can be misleading—dynamic advancing/receding angles and time-stamped measurements better capture hysteresis, roughness, contamination, and absorption effects. Use Young–Laplace fitting for more consistent droplet-shape analysis when axisymmetry holds, and use dynamic surface tension when fast interface changes drive outcomes (dispensing, foaming, wetting/leveling, drying/coating).
Business value: Better control of wettability and interfacial behavior improves coating holdout, grease/water resistance, print quality, and adhesive/label performance—reducing scrap, customer complaints, and line downtime. Surface measurements also support circularity goals by improving de-inking/cleaning performance in mechanical recycling and accelerating development of compostable or bio-based packaging films with predictable moisture behavior.
Standards to follow: Follow TAPPI T 458 / ASTM D724 for porous paper and paperboard wettability using fixed-time (time-stamped) angle-of-contact reporting for sizing and holdout QC. For broader, reproducible wettability/SFE workflows and dynamic angles/roll-off behavior, align methods with the ISO 19403 series, and document controlled conditioning, timestamps, and pass/fail data-quality rules to keep QC trending comparable.
Bottom line: This is a practical, packaging-focused playbook for choosing the right surface measurement, running it in a repeatable way, and translating the numbers into decisions that improve barrier performance, print/recycle outcomes, and adhesion—while supporting sustainability-driven material shifts. It helps teams move from trial-and-error to measurable, spec-driven surface control across paper, films, coatings, and finished packs.

Kapitel 1: Einführung

In today’s packaging and container industry, success is determined by factors such as product quality, user experience, and environmental impact. This can be illustrated through a simple yet detailed example: oil and grease-resistant paper, a crucial component of the modern packaging industry. Despite the hydrophobicity and porosity of the base paper making it unsuitable for packaging purposes, a coating with specific properties is applied to impart hydrophobic and oleophobic characteristics. These papers, derived from plant fibers, are light, flexible, recyclable, and compostable materials. Since they are derived from renewable resources they are compatible to environment. Consequently, these papers have become indispensable in the area of packaging, embodying the industry’s commitment to both efficiency and sustainability.

In the preparation of oil and grease-resistant papers, surface properties such as contact angle, sliding angle, surface tension, and surface energy play a crucial role. Therefore, the success of the packaging and container industries lies in how efficiently one can apply these surface properties to produce papers with the desired characteristics.

We use the following surface properties to understand the behavior of Packaging and Containers products and improve their quality.

Kapitel 2: Kontaktwinkelmessung

Der Kontaktwinkel quantifiziert die Benetzbarkeit einer Oberfläche, indem er den Winkel zwischen der Oberfläche einer Flüssigkeit und einer festen Oberfläche darstellt.
Dropletlab-Forschung

Sample Image taken from Droplet Lab Tensiometer.

Young – Laplace-Methode

Polynomiale Methode

Dynamischer Kontaktwinkel

Ideally, when we place a drop on a solid surface, a unique angle exists between the liquid and the solid surface. We can calculate the value of this ideal contact angle (the so-called Young’s contact angle) using Young’s equation. In practice, due to surface geometry, roughness, heterogeneity, contamination, and deformation, the contact angle value on a surface is not necessarily a single consistent value but rather falls within a range. The upper and lower limits of this range are known as the advancing and receding contact angles, respectively. The values of advancing and receding contact angles for a solid surface are highly sensitive to many parameters, such as temperature, humidity, homogeneity, and minor contamination of the surface and liquid. For example, the advancing and receding contact angles of a surface can differ at different locations.

Dynamischer Kontaktwinkel versus statischer Kontaktwinkel

Praktische Oberflächen und Beschichtungen weisen von Natur aus eine Kontaktwinkelhysterese auf, die auf eine Reihe von Gleichgewichtswerten hinweist. Wenn wir statische Kontaktwinkel messen, erhalten wir einen einzigen Wert innerhalb dieses Bereichs. Sich ausschließlich auf statische Messungen zu verlassen, wirft Probleme auf, wie z. B. schlechte Wiederholgenauigkeit und unvollständige Oberflächenbewertung in Bezug auf Haftung, Sauberkeit, Rauheit und Homogenität.

In practical applications, we need to understand how easily a liquid spreads (advancing angle) and how easily it is removed (receding angle), such as in painting and cleaning. Measuring advancing and receding angles offers a holistic view of liquid-solid interaction, unlike static measurements, which yield an arbitrary value within the range.

Diese Erkenntnisse sind entscheidend für reale Oberflächen mit Variationen, Rauheit und Dynamik und helfen Branchen wie Kosmetik, Materialwissenschaft und Biotechnologie bei der Gestaltung effektiver Oberflächen und der Optimierung von Prozessen.

Erfahren Sie, wie die Kontaktwinkelmessung mit unserem Tensiometer durchgeführt wird

Für ein vollständigeres Verständnis der Kontaktwinkelmessung lesen Sie unsere Kontaktwinkelmessung: Der endgültige Leitfaden

Open Benchmark Data: Contact Angle & Surface Energy

These reference measurements show how deionized water wets four standard substrates measured with the Droplet Lab Dropometer. Use them as visual and numerical benchmarks when you're checking your own sample preparation, treatments, and chemistry.

Full contact angle and surface energy datasets (including additional liquids and statistics) are available on our dataset hub.

Glass - DI Water
Glass - DI Water
Nylon - DI Water
Nylon - DI Water
PMMA - DI Water
PMMA - DI Water
Teflon - DI Water
Teflon - DI Water

The droplet images above are taken from the same benchmark series as our open dataset. For each substrate and probe liquid we report:

● Advancing and receding contact angles (and hysteresis)
● Derived surface energy (SFE) values based on multi-liquid measurements
● Measurement conditions, uncertainties, and sample preparation details

Comparing your own droplet shapes and angles against these references is a fast way to spot contamination, treatment drift, or unexpected changes in wettability.

Kapitel 3: Messung der Oberflächenspannung

Diese Eigenschaft misst die Kraft, die auf die Oberfläche einer Flüssigkeit wirkt, mit dem Ziel, ihre Oberfläche zu minimieren.

Messung der Oberflächenspannung

Sample Image taken from Droplet Lab Tensiometer

Dynamische Oberflächenspannung

Die dynamische Oberflächenspannung unterscheidet sich von der statischen Oberflächenspannung, die sich auf die Oberflächenenergie pro Flächeneinheit (oder die Kraft, die pro Längeneinheit entlang des Randes einer flüssigen Oberfläche wirkt) bezieht.

Die statische Oberflächenspannung charakterisiert den Gleichgewichtszustand der Grenzfläche von Flüssigkeiten, während die dynamische Oberflächenspannung die Kinetik von Änderungen an der Grenzfläche berücksichtigt. Diese Veränderungen können das Vorhandensein von Tensiden, Additiven oder Schwankungen in Temperatur, Druck und Zusammensetzung an der Grenzfläche beinhalten.

Wann sollte die dynamische Oberflächenspannungsmessung verwendet werden?

Dynamic surface tension is essential for processes that involve rapid changes at the liquid-gas or liquid-liquid interface, such as droplet and bubble formation, coalescence (change in surface area), the behavior of foams, and the drying of paints (change in composition, e.g., evaporation of solvent). It is measured by analyzing the shape of a hanging droplet over time.

Die dynamische Oberflächenspannung gilt für verschiedene Branchen, darunter Kosmetika, Beschichtungen, Pharmazeutika, Farben, Lebensmittel und Getränke sowie industrielle Prozesse, in denen das Verständnis und die Kontrolle des Verhaltens von Flüssigkeitsgrenzflächen für die Produktqualität und Prozesseffizienz unerlässlich ist.

Erfahren Sie, wie die Messung der Oberflächenspannung mit unserem Tensiometer durchgeführt wird

Für ein vollständigeres Verständnis der Oberflächenenergiemessung lesen Sie unsere Oberflächenspannungsmessung: Der endgültige Leitfaden

Kapitel 4: Messung der Oberflächenenergie

Die Oberflächenenergie bezieht sich auf die Energie, die erforderlich ist, um eine Flächeneinheit einer neuen Oberfläche zu erzeugen.
231

Sample Image taken from Droplet Lab Tensiometer

Erfahren Sie, wie die Messung der Oberflächenenergie mit unserem Tensiometer durchgeführt wird

Für ein umfassenderes Verständnis der Oberflächenenergiemessung lesen Sie unsere Oberflächenenergiemessung: Der ultimative Leitfaden

For benchmark contact angle and surface energy values on glass, nylon, PMMA, and Teflon, see the Open Benchmark Data panel above or visit our Dataset Hub for full CSV downloads.

Kapitel 5: Gleitwinkelmessung

Der Gleitwinkel misst den Winkel, in dem ein flüssiger Film über eine feste Oberfläche gleitet. Es wird häufig verwendet, um die Rutschhemmung einer Oberfläche zu beurteilen.

Gleitwinkel 1

Sample Image taken from Droplet Lab Tensiometer

Erfahren Sie, wie die Gleitwinkelmessung mit unserem Tensiometer durchgeführt wird

Für ein umfassenderes Verständnis der Gleitwinkelmessung lesen Sie unsere Gleitwinkelmessung: Der endgültige Leitfaden

Kapitel 6: Anwendungen in der Praxis

Within the Packaging and Containers industry, several case studies exemplify the advantages of conducting surface property measurements.

Soyhull-Derived Biodegradable Packaging Films: Using Water Contact Angle to Quantify Surface Wettability and Moisture Sensitivity

Due to their inability to biodegrade, petroleum-based plastics pose significant environmental challenges by disrupting aquatic, marine, and terrestrial ecosystems. Additionally, the widespread presence of microplastics and nanoplastics induces serious health risks for humans and animals. These pressing issues create an urgent need for designing and developing eco-friendly, biodegradable, renewable, and non-toxic plastic alternatives. To this end, agro-industrial byproducts such as soyhulls, which contain 29–50% lignocellulosic residue, are handy. This study extracted lignocellulosic residue from soyhulls using alkali treatment, dissolved it in ZnCl2 solution, and crosslinked it with calcium ions and glycerol to create biodegradable films. The film formulation was optimized using the Box–Behnken design, with response to tensile strength (TS), elongation at break (EB), and water vapor permeability (WVP). The optimized films were further characterized for color, light transmittance, UV-blocking capacity, water absorption, contact angle, and biodegradability. The resulting optimized film demonstrated a tensile strength of 10.4 ± 1.0 MPa, an elongation at break of 9.4 ± 1.8%, and a WVP of 3.5 ± 0.4 × 10−11 g·m−1·s−1·Pa−1. Importantly, 90% of the film degrades within 37 days at 24% soil moisture. This outcome underscores the potential of soyhull-derived films as a sustainable, innovative alternative to plastic packaging, contributing to the circular economy and generating additional income for farmers and allied industries.

Role of the Droplet Lab Goniometer

The authors used a Droplet Lab Dropometer to measure water contact angle (WCA) on the optimized soyhull-extract (SHE) film—directly quantifying the film’s surface wetting behavior (hydrophilicity/hydrophobicity), which is central to packaging performance where moisture exposure, surface interactions, and barrier behavior matter. The paper explicitly reports that WCA was measured using a Dropometer (Droplet Lab, Markham, ON, Canada) and evaluated over time (0, 10, 20, 30 s) to observe changes after droplet placement.

Key Findings

  • Optimized packaging film performance: The optimized film achieved TS = 10.4 ± 1.0 MPa, EB = 9.4 ± 1.8%, and WVP = 3.5 ± 0.4 × 10−11 g·m−1·s−1·Pa−1.
  • Validated optimization approach: Predicted vs. experimental TS/EB/WVP were statistically consistent (no significant differences reported).
  • Surface wettability quantified by Dropometer: The film surface is hydrophilic (WCA < 90°) and WCA decreased from ~76.9° (0 s) to ~49.2° (30 s), indicating increasing wetting/spreading/interaction with water over time.
  • Relevance vs conventional plastics: The authors note LDPE is more hydrophobic (reported WCA ~100.7°), and they discuss pathways (e.g., incorporating hydrophobic components like lignin/waxes) to improve water resistance.

End-of-life advantage: The film shows rapid biodegradation (reported ~90% degradation within 37 days at 24% soil moisture in the abstract).

Why It Matters

For packaging teams developing bio-based film structures, contact angle is a fast, quantitative way to screen whether a new film will behave more like a moisture-sensitive, hydrophilic biopolymer (potentially needing coatings/lamination) versus a more water-repellent packaging surface. Here, the Dropometer WCA time-series reveals that the soyhull-derived film wets increasingly over 30 seconds—information that can directly inform coating selection, surface treatments, and QC specs when targeting real-world humidity/water exposure while still benefiting from strong biodegradability and sustainability claims.

Method Snapshot

Optimized soyhull-extract (SHE) biodegradable film; sessile water droplet contact angle measured with a Droplet Lab Dropometer (0.05 µL precision dropper) and analyzed with sessile-drop software; WCA tracked at 0/10/20/30 s after droplet placement (static sessile-drop measurement; exact test temperature and liquid surface tension not reported).

Data Note

  • Time-resolved contact-angle measurements at 0, 10, 20, and 30 seconds and reported angles (76.9°, 58.3°, 52.7°, 49.2°) illustrating increased hydrophilicity over time
Figure

Citation (APA Format)

Regmi, S., Paudel, S., & Janaswamy, S. (2024). Development of eco-friendly packaging films from soyhull lignocellulose: Towards valorizing agro-industrial byproducts. Foods, 13(24), 4000. https://doi.org/10.3390/foods13244000

View Publication →

Verlust der Sterilität der Verpackung aufgrund von Leckagebildung

Herausforderung: Die Sterilität aseptischer Verpackungen kann während der Lagerung und des Vertriebs durch grobe oder unsachgemäße Handhabung beeinträchtigt werden.

Lösung: In one study, scientists focused on determining the threshold pressure required to create a leak. They observed significantly lower threshold pressures in the case of low surface tension liquids, such as safranin red dye, compared to high surface tension liquids, like distilled water. This insight allows manufacturers to proactively avoid conditions that could lead to leakage issues. A tensiometer like Droplet Lab's Dropometer precisely measures surface tension, enabling manufacturers to identify and understand how different liquids interact with packaging materials. By providing accurate data on surface tension, it helps in assessing the susceptibility of packaging to leaks and supports the development of more robust packaging solutions, thus maintaining package sterility.

Verlust der Sterilität der Verpackung aufgrund von Leckagebildung

Removal of Printing Ink in Mechanical Recycling Process

Herausforderung : Printing ink in flexible packaging materials can cause contamination in the mechanical recycling process.

Lösung : The removal of printing ink residue from the surface of flexible plastic packaging can be achieved through detergency, mechanical, and chemical cleaning processes. In this context, contact angle measurements are invaluable for studying the interaction between the polymer and surfactant. These measurements are highly effective in comparing the wetting behavior of surfactants on various printing ink systems and non-printed film surfaces.

Removal of Printing Ink in Mechanical Recycling Process

Improving Label Adhesion on Curved Surfaces

Herausforderung : There was a big issue with label adhesion in packages that have curved surfaces, resulting in peeling and poor aesthetics.

Lösung : The manufacturer applied the surface tension measurements that helped in the selection of label materials with appropriate adhesive properties for curved surfaces. These optimized properties of adhesives ensured strong and lasting label adhesion, enhancing the overall visual appeal of the packaging.

Improving Label Adhesion on Curved Surfaces

Wir sind Ihre Partner bei der Lösung Ihrer geschäftlichen und technologischen Probleme herausforderungen

Wenn Sie an der Implementierung dieser oder anderer Anwendungen interessiert sind, kontaktieren Sie uns bitte.

Kapitel 7: Normen und Richtlinien

In an industry where precision reigns supreme, how can Packaging and Containers manufacturers ensure their products withstand scrutiny? The answer lies in standards and guidelines: the compass that guides them through the complex maze of quality and performance.

TAPPI T 458 — Surface Wettability of Paper (Angle-of-Contact Method) / ASTM D724

What it is

A standardized sessile-drop contact angle method for porous paper/paperboard surfaces that quantifies resistance to wetting at a defined early time and how that apparent wettability changes over time. It’s commonly used as a practical, time-stamped wettability/absorption index for sizing control and process runnability.

When to use it

Sizing / holdout QC for printing, converting, and aqueous coating

Use fixed-time angles to detect lot-to-lot or roll-to-roll drift before it becomes press/coater waste.

Non-uniformity troubleshooting (directional + sidedness)

Use MD vs CD and wire vs felt sampling to identify where wetting/penetration behavior differs across the web.

In-scope / Out-of-scope

In scope
  • Porous paper and paperboard grades where wetting and penetration occur simultaneously.
  • Sessile-drop contact angle measured at defined timestamps (fixed-time reporting).
  • Initial + time-evolution reporting (early-time angle plus later-time angle and/or a rate-of-change indicator).
  • Controlled sample conditioning/environment per lab SOP (commonly aligned to standard paper conditioning atmospheres).
Out of scope
  • Universal “good/bad” cutoffs that transfer across different porous grades without site/grade calibration.
  • Mass-based absorbency / water uptake (use Cobb / TAPPI T 441 or similar when you need absorption by mass).
  • Advancing/receding angles, hysteresis, or dynamic surface tension characterization requirements.
  • Cases where the drop fully absorbs before the required timestamp: report as “not measurable at X s” rather than forcing a number (use a separate early-time/high-speed internal metric if needed).

Minimum you must report (checklist)

  • Substrate description: grade/structure, basis weight (or caliper), sizing/coating type if known, and side + orientation (wire/felt; MD/CD) where applicable.
  • Conditioning conditions: temperature/RH (and conditioning time/atmosphere).
  • Test liquid(s): identity (DI water baseline if used) and liquid temperature (if controlled).
  • Drop volume + dispense details: volume, delivery method (needle/tip), and any height/placement controls.
  • Defined timestamps: the exact capture times (e.g., 5 s and 60 s) and how “time zero” is set (e.g., first frame after dispense).
  • Reported metrics: θ@5s, θ@60s, and Δθ(5→60s) (or your defined change metric).
  • Replicates + statistics: replicate count per zone and summary statistic (median or mean) plus variability (IQR or SD).
  • Data-quality rules: exclusion criteria (distorted footprint/failed edge detection, sheet not flat/secured, drop disappears early) and how exclusions are recorded.

On porous sheets the apparent contact angle is time-dependent due to simultaneous wetting and penetration, so angles without a timestamp are not comparable. Automating fixed-time capture improves repeatability, but pass/fail limits must be calibrated per grade family against real print/coating/converting outcomes.

How to interpret results (guardrails)

  • Only compare like-for-like: same liquid, drop volume, conditioning, optics/settings, and timestamps—treat angles as protocol-specific indices, not universal constants.
  • θ@5s (early-time index): lower values generally indicate faster early wetting (less resistance/holdout), while higher values indicate more early-time resistance under that SOP.
  • Δθ(5→60s) (change-over-time index): a larger magnitude drop in angle typically signals faster evolution (often penetration/absorption-dominated on porous sheets), but confirm root cause with complementary process/context data when needed.
  • Variability and deltas are actionable signals: spikes in IQR/SD, strong MD–CD differences, or wire–felt differences often predict non-uniform converting/printing behavior even when the overall median looks “on target.”

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We hope this guide showed you how to apply surface science in the Packaging and Containers industry.

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